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修复氯化溶剂场地的工具和方法.pdf

上传人: le****ng 编号:187027 2024-12-17 48页 108.60MB

1、Identifying and Delineating Hidden Sources Within a Larger Chlorinated Solvent PlumeKristin Robrock,Ph.D.,P.E.and Peter Mesard,P.E.,P.G.,C.Hg.ExponentOakland,CAOutline Commingled plume problem at site Methodology Results and suggestions for implementationCommingled Plume Problem TCE,PCE,and other ch

2、lorinated solvents are commonly commingled at contaminated sites and in groundwater at industrial urban areas How to distinguish and delineate where one plume ends and another begins?Particularly difficult when different sites have released the same chemicalIs all this ours?Site A being blamed for a

3、ll TCE in plume Objectives:Is all this TCE from Site A?If not,what are the other sources?Can we delineate the extent of Site A TCE?Complicated site with multiple on-site sources Site operated 1907 present Multiple vapor degreasers Degreasers moved locations over time Multiple different solvents over

4、 timeSite AGroundwater flow complicated by hydraulic divide Groundwater divide due to pumping Divide appeared 1970 On-site pumping wells impacted groundwater flow locallyTCE contours suggest other contributors to the plume TCE contours show hot spots and anomalies inconsistent with the direction of

5、groundwater flow TCE flowing onto Site from upgradient source(s)PCE plume looks very different from TCE PCE plume ends shortly downgradient of Site A Similar short plumes for other solvents,like 1,1,1-TCA Therefore,there must be other sources of TCEMany suspicious industrial sites in the area Site i

6、n an urban industrial area Many historical metal plating facilities,machine shops,dry cleaners,and other industrial sites with the potential to have used and released chlorinated solventsPotential chlorinated solvent users may explain TCE anomalies TCE hotspots located adjacent to documented chlorin

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本文主要介绍了如何识别和界定一个更大的氯化溶剂污染羽流中的隐藏源。主要内容包括: 1. 污染羽流问题:三氯乙烯(TCE)、四氯乙烯(PCE)和其他氯化溶剂在工业城市地区的污染场地和地下水中常见混合。 2. 方法论:通过准备“指纹”由“饼图”组成,识别匹配现场和那些不匹配的指纹;沿羽流中心线绘制污染物浓度,识别匹配现场和不匹配的指纹;使用匹配现场的指纹拟合一阶衰减曲线,外推隐藏羽流的距离。 3. 结果和建议:该方法简单、易于实施,使用现有、常规数据,最好与一致的采样位置和沿羽流中心线的采样位置一起使用。 4. 案例研究:通过案例研究展示了该方法的有效性。 5. 结论:一个强大的地质模型是成功的关键。
如何识别和区分地下水中的混合污染源? 如何利用环境地层学改善污染场地地质模型? 如何量化地下水中的自然衰减过程?
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