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PFAS 处理:有关科学和应用现状的更多信息.pdf

上传人: le****ng 编号:187023 2024-12-17 34页 6.85MB

1、Evaluation of PFAS Removal by Surface Active Foam Fractionation and Destruction by Electrochemical OxidationHanna Temme,PhDLaura LewisRebecca MoraProject Area Twin Cities east metro area,Minnesota Over 125 sq miles of PFAS impacted groundwater and surface water PFOS ImpactsFeasibility Study Completi

2、ng a feasibility study for Minnesota Pollution Control Agency(MPCA)to address PFAS impacts MPCA considering multiple technologies and treatment train alternatives Specifically considering technologies that may reduce filtration mediaPossible Treatment Train Surface Active Foam Fractionation(SAFF)one

3、 possible technology SAFFcould be used as a standalone technology or as pretreatment to filtration to reduce costs Pilot study focused on SAFFPre-Treatment followed by destruction of concentrateSAFF Pre-TreatmentGAC/IX PolishingPFAS Impacted Surface Water and GroundwaterDisposal or DestructionSecond

4、ary FractionateSAFF EffluentClean Water for Distribution,Injection,or DischargeSpent MediaSurface Active Foam Fractionation(SAFF)1.Inject air into water2.PFAS foams3.Remove foamPilot study used a SAFF20 from EPOCNo surfactants usedSAFF:Two Stages ProcessPrimary Fractionation Goal:Minimize PFAS conce

5、ntration in effluentSecondary FractionationGoal:Minimize volume of PFAS concentrate prior to destruction or disposalFoam and top layer of water flow over cone and captured in top hoodInjected air bubbles promote foam formationPFAS foam vacuumed offInjected air bubbles promote foam formation and carr

6、y PFAS upwardWater SourcesSite selected because of access to impacted surface water and impacted aquifersRaleigh CreekShakopee Aquifer Monitoring WellFoam readily forms on Raleigh CreekPFOSPFOATotal Organic CarbonRaleigh Creek2,000-3,000 ng/L700-900 ng/L6.5 mg/LShakopee Aquifer950 ng/L330 ng/L0.5 mg

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本文主要介绍了PFAS(全氟和多氟烷基物质)的去除和破坏技术。主要内容包括: 1. 表面活性泡沫分馏(SAFF®)技术可以有效去除PFAS,并将其浓缩。该技术通过向水中注入空气,使PFAS形成泡沫,然后去除泡沫,从而实现PFAS的去除和浓缩。 2. 电化学氧化技术可以破坏SAFF®浓缩后的PFAS。该技术通过在电极之间转移电子,逐步去氟化PFAS,从而实现其完全矿化。 3. 实验表明,SAFF®技术可以有效去除和浓缩PFAS,即使在泡沫不形成的情况下也能实现。电化学氧化技术可以破坏SAFF®浓缩后的PFAS,实现其完全矿化。 4. 实验还发现,通过调整SAFF®的设置,可以降低PFAS的出水中浓度,但会增加PFOA的出水中浓度。 5. 实验还表明,通过调整电化学氧化技术的参数,可以控制氢气和氢氟酸的排放,并最小化PFAS的气溶胶化。 6. 下一步计划评估SAFF®在不同的水源中的性能,并与其他PFAS破坏技术进行比较。
如何通过表面活性泡沫分馏去除PFAS? 电化学氧化如何有效破坏PFAS? 优化GAC性能以提高PFAS去除效果?
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