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用于防护涂料应用的抗紫外线环氧树脂的评估.pdf

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1、Advanced MaterialsEvaluation of UV Resistant Epoxies for Protective Coating ApplicationsMitch BuchananTechnical Account Manager,InfrastructureHuntsman Advanced Materials Safety Share Experiment purpose and overview Low yellowing epoxies Experiment plan Evaluation results System properties QUV-A resu

2、lts Conclusion and questionsAgendaCTT Summit2Safety ShareCTT Summit3Experiment purpose and overview4 Epoxy based protective coatings Typically provide excellent adhesion,chemical resistance,strength,and durability Limited gloss retention and yellowing resistance under UV exposure Most common epoxide

3、s have aromatic chemical structure In use often aliphatic polyurethane,polyurea or acrylic topcoats are specified Cycloaliphatic resins and hardeners allow formulation of epoxies for maximized UV stability Cycloaliphatic systems have better gloss retention and reduced yellowing compared to standard

4、aromatic epoxies but are often hindered by slow cure times without heat Low yellowing epoxy systems could eliminate the need for a traditional 3 coat system Potential to reduce project time and raw material costs with 1 or 2 coat systemsPurpose of experimentExperiment purpose and overview5 Neat resi

5、n&hardeners(unmodified and without filler)evaluated as clear coatings 3 cycloaliphatic epoxy resins and 3 formulated cycloaliphatic amines hardeners Aromatic Bis-A DGE liquid epoxy resin was used as the epoxy control Solvent borne polyurethane based clear top coating used as a commercial technology

6、benchmark Testing Protocol Physical properties were measured on standard Q-panels QUV-A exposure test according to ASTM G-53 using clear glass panelsExperiment ParametersExperiment purpose and overview6Raw Material SpecificationsExperiment purpose and overview7NumberTypeSolids Content%Color,GardnerV

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本文主要评估了UV抵抗性环氧树脂在保护涂层应用中的性能。实验比较了三种加速的环氧树脂(A、B、C)和三种环氧胺硬化剂(D、E、F)的组合,以及一个商业对照组。结果显示,含有环氧丙烷基团的环氧树脂和环氧胺硬化剂组合(C-2)在物理性质、耐UV光性能和光泽保持方面表现最佳。而传统的芳香族环氧树脂(A)在500小时UV暴露后明显黄化,并在1000小时内失效。加速的环氧树脂系统提高了固化速度,同时保持了良好的机械和物理性能。在3000小时的UV暴露后,测试的环氧脂质系统显示出良好的UV抵抗性,无需使用UV吸收剂或光稳定剂。未来的工作将包括进一步开发UV抵抗性树脂和加速固化的硬化剂,以及在配方系统中添加功能性添加剂(如UV稳定剂、UV抑制剂等)。
"UV抵抗性环氧树脂性能评估" "如何提高环氧树脂的耐黄变性?" "快速固化环氧树脂系统的研究进展"
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