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用于膨胀型乳胶漆的支链乙烯基酯共聚物.pdf

上传人: c** 编号:465032 2025-01-12 28页 4.54MB

1、CONFIDENTIALSeptember 10,20241Branched Vinyl Ester Copolymers forIntumescent Emulsion PaintsCoatings Trends&Technologies SummitSeptember 5,2024Nathalie HavauxCONFIDENTIALSeptember 10,20242Content1.Intumescent Coatings2.Highly Aliphatic Vinyl Ester3.Performance4.ConclusionsSectionCONFIDENTIALSeptembe

2、r 10,20243Intumescent Coatings1CONFIDENTIALSeptember 10,20244Building FiresThe need for better fire protectionResidential fires cause an estimated 3000 deaths in the USA and 5000 in EU each yearUK 2017,73 deadSpain 2024,10 deadChina 2024,15 deadCONFIDENTIALSeptember 10,20245Structural Protection wit

3、h Intumescent CoatingsBasicsSource:ClariantUnprotected steelSteel protected withintumescent coatingSteel protected with intumescentcoating in a fire scenarioSteel with intumescent:tests complianceApplication:airless-spray,brush,roller500C:Steel strength lossFire resistance 3 times cellulosic fires.F

4、ire Types and Intumescent CoatingsCELLULOSIC FIRESHYDROCARBON/JET FIRESMainly Vinylics,(Styrene)/Acrylics(50%WB,25%SB,25%HS EP)Combustible:timber,paper,furniture,textile500C reached in 5 min.CONFIDENTIALSeptember 10,20249Fire Types and Intumescent CoatingsCELLULOSIC FIRESMainly Vinylics,(Styrene)/Ac

5、rylics(50%WB,25%SB,25%HS EP)Combustible:timber,paper,furniture,textile.500C reached in 5 min.EpoxiesCombustible:oil,gas.1000C reached in 5 min.Radiation value:3 times cellulosic fires.HYDROCARBON/JET FIRESCONFIDENTIALSeptember 10,202410Waterborne Cellulosic Intumescent CoatingsCurrent trends&unmet n

6、eedsGrowing market worldwideLooking for:Longer protection(2h)Application easiness/thin layers Outdoor durabilityStyrene/Acrylic,All Acrylic and Vinylic binders can be used for this applicationVinyl acetate-based binders provide best intumescent performance for cellulosic fireVinyl neodecanoate is th

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本文主要探讨了含分支状乙烯酯共聚物的膨胀型防火涂料的研究与应用。文章指出,这种涂料能在火灾情况下,通过热膨胀形成保护层,降低建筑结构的温度,延长其承受火焰的时间。研究表明,增加乙烯酯单体的含量可以提高涂料的膨胀系数和防火性能。特别是,含有分支状结构的乙烯酯单体(Vinyl Neodecanoate)的共聚物,因其特殊的分子结构,在膨胀型防火涂料中表现出优异的性能。例如,当乙烯酯单体含量为30%时,涂料的膨胀系数可达48,而100%的乙烯酯单体含量时,膨胀系数可达52。此外,Vinyl Neodecanoate还具有良好的耐水性和耐化学品性,适合用于半暴露条件下的建筑结构。文章最后强调了乙烯酯单体在提高膨胀型防火涂料性能方面的潜力,并呼吁进一步的研究与开发。
如何提升涂料性能?" 如何理解Intumescent Coatings的工作原理?" Vinyl Neodecanoate单体如何改变防火涂料的未来?"
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