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食品和食品包装中 PFAS 的分析.pdf

上传人: sec****ies 编号:734745 2025-07-26 27页 3.15MB

1、Analysis of PFAS in food and food packagingSolving the problems of“forever chemicals”in agricultureAgricultural Outlook Forum,February 27,2025Yelena SapozhnikovaUS Department of Agriculture(USDA),Agricultural Research Service(ARS),Wyndmoor,PA,USAARS mission:Develop and share solutions to agricultura

2、l problems that impact the United States Ensure a safe and high-quality food supply Develop new technologies and knowledgeProtecting public health Developing strategies and technologies to protect food from pathogens,toxins,and chemical contaminantsMeeting regulatory requirements Ensuring that food

3、and feed meet domestic and foreign regulatory requirementsImproving agriculture Enhancing the quality and utilization of agricultural commoditiesReducing foodborne pathogens Developing tests and processes to reduce and control pathogens and toxins in agricultural productsThe USDAs National Program 1

4、08,Food Safety,is a research-based program that aims to keep the U.S.food supply safeAdapted from Evich et al.Science 2022PFAS widespread contaminationDiet is a major exposure pathway:Food products Cookware and bakeware Food packaging Processing equipment Drinking water Food of animal origin is cons

5、idered one of the major pathways for human exposure According to European Food Safety Authority(EFSA),fish and other seafood account for up to 86%of dietary PFAS exposure in adultsLDQuick,easy,cheap,effective,rugged,safe,efficient,and robust(QuEChERSER)sample preparation mega-methodNew methods for P

6、FAS analysisBeefChickenCatfishPorkLiquid EggsPowdered Eggs1 g sampleQuEChERSERextraction5 mL acetonitrile/waterPFAS analysis(100)Veterinary Drugs and Pesticides(325)Pesticides and Persistent Organic Pollutants(POPs)(275)Gas chromatography-mass spectrometry analysisLiquid chromatography-mass spectrom

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本文主要关注PFAS(全氟和多氟烷基物质)在食品和食品包装中的分析,以及农业中“永久性化学物质”问题的解决。以下为关键点: 1. 美国农业部(USDA)致力于解决影响美国的农业问题,确保食品安全和质量,并开发新技术和知识。 2. PFAS广泛污染,饮食是主要暴露途径,尤其是动物源性食品。 3. 研究采用QuEChERSER方法新分析PFAS,检测到多种PFAS在肉类、鸡蛋等食品中。 4. 海鲜试点研究显示,在74%的测试样本中检测到8种PFAS,其中PFHxS最常检测到。 5. 消费者的选择对PFAS分布无显著差异,野生与养殖海鲜无差异。 6. 欧洲食品安全局(EFSA)设定的耐受阈值表明,部分欧洲人群的PFAS暴露已超出安全范围。 7. 食品包装样本分析发现,84%的样本至少含有一种PFAS,含量从0.4到224ng/g不等。 8. 高分辨率质谱非目标分析确认了5种新的PFAS。 核心数据引用: - EFSA设定的耐受阈值:每周4.4ng/kg体重(PFOS+PFOA+PFNA+PFHxS)。 - 海鲜样本中∑PFAS含量范围:0.12-20ng/g。 - 食品包装样本中∑PFAS含量范围:0.4-224ng/g。
"食物中PFAS有多普遍?" "如何检测食品中的PFAS?" "海鲜中PFAS含量有多高?"
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