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有机硅氧烷表面活性剂作为永久性化学品的替代品——反应型与非反应型.pdf

上传人: 散** 编号:1277086 2026-07-11 26页 2.80MB

1、Organo-siloxane Surfactant asSubstitute for Forever Chemicals-Reactive versus Non-reactiveEvaluation in Waterborne Epoxy CoatingsSteve Crain,PMPDirector of Business DevelopmentCASE and PU AdditivesJay Liu,Ph.D.Technical Director CASESeptember 3-5,2025CTT 2025 Chicago Technical Paper1El CorporationSe

2、ptember 3-5,2025CTT 2025 Chicago Technical Paper2Established in 1945 El Corporation(pronouncedE-LAY)is a leading manufacturer of specialty and intermediateadditives used in a wide variety of industries.These industriesinclude rigid polyurethane,metalworking,personal care andC.A.S.E.Els current focus

3、 is on technologies utilizing sustainablematerials including upcycling,recycling and enzymatictechnologies.Partnering with innovators like ourselves to bringenvironmentally useful and beneficial chemistries to the world.Company ProfileSeptember 3-5,2025CTT 2025 Chicago Technical Paper3Additive and I

4、ntermediateManufacturerISO 9001:2015 CertifiedEcoVadis Silver MedalOver 100 Years of TechnicalExpertise and KnowledgeLocated near Chicago,ILPrivately OwnedSeptember 3-5,2025CTT 2025 Chicago Technical PaperAs a leader in innovation,sustainability and marketresponsiveness to ensure that our customers

5、havesolutions they need today and in the future;EleCorporation is continually making strategicinvestments to deliver advanced and cleanertechnologiesResearch Development and EngineeringResearch in RenewableTechnologiesInvestment in Research andDevelopmentFacility and EngineeringAdvancementsEngage in

6、 StrategicPartnerships4PTFE is Non-PBTHigh molecular weightLower solubilityReduced bioavailabilityDifferent risk profile vs PFOABut PersistentPrevious production Intermediates are banned in US,etc.Some countries not yet aligned(China)sourced PTFE maycontain trace PFOA,etc.REACH proposal on universal

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1. **核心目标**:用有机硅氧烷表面活性剂替代“永久化学品”PTFE,在水性环氧涂料中评估反应性与非反应性性能。 2. **关键数据**: - **耐磨性**:有机硅氧烷(5PHR)的Tabor磨损指数(20-50mg/1000周期)显著优于PTFE(未提供具体值),且线性(LIN)和支化(BR)类型均提升耐磨性。 - **摩擦系数**:5PHR添加量下,所有有机硅氧烷的静态COF降低(0.2-0.8),优于PTFE(未提供具体值)。 - **附着力与冲击**:划格附着力达满分(5),冲击强度优于PTFE,但支化蜡(MW)表现较差。 - **表面性能**:接触角(50-70°)与光泽无显著变化,不影响后续涂层附着力。 3. **优势**:有机硅氧烷为低粘度液体,非永久化学品,可调节极性与功能,适用于多种体系。
**"硅烷替代PTFE?"** (吸引关注环保涂料研发的技术人员,突出创新替代方案) **"耐磨性如何提升?"** (针对涂料性能优化的工程师,强调关键性能指标) **"环保涂层新选择?"** (吸引可持续材料领域的决策者,突出环保与功能性结合)
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